ni-rich neutrons · where the nickel sits from Fadila El Kouihen's thesis to neutron and synchrotron beam time · Abdessamad Faik (UM6P), Irene Urcelay-Olabarria and Josu M. Igartua (EHU) · November 2026

Sources

Sources

Everything this site leans on, with its status: read in full here, checked by a search on the date given, or not checked. The literature was searched on 3 November 2026; DOIs were seen on Crossref or PubMed Central and abstracts read; full texts are still to be read before any number of theirs enters a proposal.

43 sources: 4 read in full here, 39 confirmed by a search on the date given, 0 cited from memory and still to be confirmed. Generated from data/sources.yml; do not edit by hand.

The thesis and its review

Key Reference Status Used for
elkouihen-rev F. El Kouihen, Synthesis and Characterization of Novel Nickel-Rich Cathode Materials for Conventional Lithium-Ion and All-Solid-State Batteries, PhD thesis, UM6P (LIMSET), supervisors A. Faik and M. Chakir; revised manuscript, 17 October 2026, 258 pp. Defence 4 November 2026. read 2026-11-03
Chapter II read in full here; Chapters III–IV for their numbers
Every number of the fact base; every "thesis says" of the gaps.
igartua-l2-f J. M. Igartua, referee's Level-2 analysis of the thesis (submitted → revised), October 2026. read 2026-11-03 The structural inconsistencies (the NMA cells, the c/a text, the Fe/Sb–NMA formula, the asserted Sb\(^{5}\)⁺) behind F05 and F07.
llzo-neutrons llzo-neutrons, the companion project on Z. Kharbouch's garnet electrolytes: method, instruments, contrast, BPR.
Source / publisher
read 2026-11-03 The method, the instruments and the access rules, shared.

Structures, tables and the application

Key Reference Status Used for
sears1992 V. F. Sears, Neutron scattering lengths and cross sections, Neutron News 3 (1992) 26–37.
doi: 10.1080/10448639208218770
checked 2026-11-03
values as carried by diff-ref-struct's table (CrysFML) for b; absorption cross sections from the same table, from memory
Scattering lengths and absorption (Contrast page).
drs diff-ref-struct, the Rietveld application of J. M. Igartua (EHU); core binary drs, build of 2 November 2026: drs sf (structure factors, X-rays and neutrons, CrysFML tables), drs simulate, joint refinement module.
Source / publisher
read 2026-11-03 Every structure factor of the Contrast page; the refinements of P1–P2.

Facilities (read on their own pages, 3 November 2026)

Key Reference Status Used for
ill-d2b ILL, D2B characteristics and instrument layout.
Source / publisher
checked 2026-11-03 P1.
ill-d20 ILL, D20 characteristics and instrument layout.
Source / publisher
checked 2026-11-03 P1 (alternative).
ill-access ILL, standard access, types of beamtime access, Director's Discretionary Time, associates and scientific members, reactor cycles.
Source / publisher
checked 2026-11-03 The two-thirds rule, the deadline of 15 February 2027, cycle 202.
ill-crg ILL, D1B (CNRS–CSIC) and XtremeD (INMA–CSIC) characteristics; Institut Néel, D1B calls.
Source / publisher
checked 2026-11-03 Spanish routes.
esrf-id22 ESRF, ID22 beamline and technical description; ID22 upgrade paper (J. Synchrotron Rad., PMC10481261).
Source / publisher
checked 2026-11-03 P2.
esrf-xas ESRF, BM23, BM25 SpLine (how to apply), BM08 LISA, BM20 ROBL beamline pages.
Source / publisher
checked 2026-11-03 P4 and the edge coverage.
esrf-access ESRF, proposal types and deadlines; BAG and HUB proposals; members and associates; non-contracting countries; operation schedule 2027 (approved 5 May 2026).
Source / publisher
checked 2026-11-03 Deadlines, membership, the 2027 runs.
battery-hub ESRF news, Launch of the Grenoble Battery Hub (ESRF, ILL, CEA), 24 November 2021; ESRF EuBat pilot HUB.
Source / publisher
checked 2026-11-03 P3, and a route for long-term access.

The candidate's published work (DOIs seen on Crossref, 3 November 2026)

Key Reference Status Used for
elkouihen2026a F. El Kouihen, M. Chakir, A. Faik, review of Co-free NMA cathodes, J. Power Sources 671 (2026) 239601.
doi: 10.1016/j.jpowsour.2026.239601
checked 2026-11-03 The candidate's own frame for NMA.
elkouihen2025 F. El Kouihen, M. Chakir, A. Faik, synthesis route and cation mixing in NMA, Chem. Pap. 79 (2025) 2411.
doi: 10.1007/s11696-025-03935-7
checked 2026-11-03 F01.
elkouihen2026b F. El Kouihen et al., Mn in LiNi0.8Co0.15−xMnxAl0.05O2, J. Energy Storage 145 (2026) 119892.
doi: 10.1016/j.est.2025.119892
checked 2026-11-03 The Mn-for-Co line, F03.

Literature: Li/Ni mixing, joint refinement, the proxy (DOIs on Crossref; abstracts read, full texts not)

Key Reference Status Used for
rougier1996 A. Rougier, P. Gravereau, C. Delmas, J. Electrochem. Soc. 143 (1996) 1168 (Li1−zNi1+zO2).
doi: 10.1149/1.1836614
checked 2026-11-03 The classic Ni-in-Li-layer reference. F01, F02.
pouillerie2001 C. Pouillerie, E. Suard, C. Delmas, J. Solid State Chem. 158 (2001) 187 (neutron diffraction of Li1−z−xNi1+zO2).
doi: 10.1006/jssc.2001.9092
checked 2026-11-03 Neutrons on Li1−zNi1+zO2. F01.
goonetilleke2023 D. Goonetilleke et al., J. Mater. Chem. A 11 (2023) 13468 (Li1−zNi1+zO2 by synchrotron, neutrons, NMR, magnetometry).
doi: 10.1039/d3ta01621h
checked 2026-11-03 Two defect regimes. F01, F02.
kurzhals2021 P. Kurzhals et al., J. Electrochem. Soc. 168 (2021) 110518 (excess Ni in LiNiO2, 1.6–3.7 %).
doi: 10.1149/1945-7111/ac33e5
checked 2026-11-03 Typical values. F01, F02.
yin2018 L. Yin et al., Rev. Sci. Instrum. 89 (2018) 093002 (neutron vs synchrotron refinement of NMC; correlations; \(\approx 0.1\,\%\) antisite sensitivity combined).
doi: 10.1063/1.5044555
checked 2026-11-03 The methods case for joint refinement. P1.
yin2020 L. Yin et al., Chem. Mater. 32 (2020) 1002 (paired antisites across NMC).
doi: 10.1021/acs.chemmater.9b03646
checked 2026-11-03 F01.
holderle2023 T. Hölderle et al., J. Power Sources 564 (2023) 232799 (ex situ high-resolution neutron diffraction of LixNCA from 18650 cells).
doi: 10.1016/j.jpowsour.2023.232799
checked 2026-11-03 Neutrons on cycled NCA. F02, F09.
trease2016 N. M. Trease et al., Chem. Mater. 28 (2016) 8170 (Al in NCA: NMR, atom probe, X-ray and neutron diffraction).
doi: 10.1021/acs.chemmater.6b02797
checked 2026-11-03 F03.
orlova2021 E. D. Orlova et al., Symmetry 13 (2021) 1628 (I(003)/I(104) and other indicators against Rietveld occupancies in NMC811).
doi: 10.3390/sym13091628
checked 2026-11-03 The proxy's limits. F01.

Literature: dopant sites

Key Reference Status Used for
weber2022 D. Weber et al., J. Electrochem. Soc. 169 (2022) 030540 (LiNi1−yMgyO2, Mg site crossover).
doi: 10.1149/1945-7111/ac5b38
checked 2026-11-03 F04.
mu2020 L. Mu et al., ACS Appl. Mater. Interfaces 12 (2020) 12874 (Mg/Mn-LiNiO2).
doi: 10.1021/acsami.0c00111
checked 2026-11-03 F04.
prado2000 G. Prado, E. Suard, L. Fournès, C. Delmas, J. Mater. Chem. 10 (2000) 2553 (Li1−z(Ni1−yFey)1+zO2: X-rays, neutrons, Mössbauer).
doi: 10.1039/b002975k
checked 2026-11-03 The Fe-site precedent. F05.
cheng2020 X. Cheng et al., J. Mater. Chem. A 8 (2020) 23293 (Sb-doped LiNiO2).
doi: 10.1039/d0ta07706b
checked 2026-11-03 F05.
wang2021 L. Wang et al., ACS Appl. Mater. Interfaces 13 (2021) 7343 (Y surface gradient).
doi: 10.1021/acsami.0c21990
checked 2026-11-03 F04.
wu2019 F. Wu et al., ACS Appl. Mater. Interfaces 11 (2019) 36751 (La2Ni0.5Li0.5O4 surface layer on NCM811).
doi: 10.1021/acsami.9b12595
checked 2026-11-03 F04.
colalongo2024 M. Colalongo et al., ACS Appl. Mater. Interfaces 16 (2024) 28683 (Zr incorporation by synchrotron XRD + XAS, co-precipitation vs lithiation).
doi: 10.1021/acsami.4c05058
checked 2026-11-03 The method template for this route. F04, P2, P4.
xin2022 F. Xin et al., Chem. Mater. (2022) (Nb in the lattice and at boundaries of NMC9055).
doi: 10.1021/acs.chemmater.2c01461
checked 2026-11-03 F10.

Literature: heating, cycling, solid state

Key Reference Status Used for
bak2014 S.-M. Bak et al., ACS Appl. Mater. Interfaces (2014) (time-resolved XRD + MS of charged NMC to 600 °C).
doi: 10.1021/am506712c
checked 2026-11-03 F06, P3.
geng2020 C. Geng et al., ACS Appl. Energy Mater. 3 (2020) 7058 (heated NMC811: gas analysis, ex situ neutrons, DSC).
doi: 10.1021/acsaem.0c01105
checked 2026-11-03 F06.
adamo2024 J. Adamo, A. Manthiram, Chem. Mater. 36 (2024) 6226 (Al or Mn in LiNiO2 and the H2–H3 transition).
doi: 10.1021/acs.chemmater.4c01033
checked 2026-11-03 F03, F09.
li2020nma W. Li, S. Lee, A. Manthiram, Adv. Mater. 32 (2020) 2002718 (NMA against NMC, NCA, NMCAM at 89 % Ni).
doi: 10.1002/adma.202002718
checked 2026-11-03 The NMA benchmark.
matras2022 D. Matras et al., J. Power Sources 539 (2022) 231589 (operando XRD-CT of an NCA 18650, ESRF ID31).
doi: 10.1016/j.jpowsour.2022.231589
checked 2026-11-03 P3 at ID31.
jousseaume2024 T. Jousseaume et al., Energy Environ. Sci. 17 (2024) 2753 (operando XRD, collapse and strain below \(\approx 40\,\%\) Li).
doi: 10.1039/d3ee04115h
checked 2026-11-03 F09.
menon2026 A. S. Menon et al., Chem. Mater. 38 (2026) 4517 (operando neutron diffraction of pouch cells, natural Li, ISIS WISH).
doi: 10.1021/acs.chemmater.5c03201
checked 2026-11-03 Natural Li in operando neutrons.
walther2021 F. Walther et al., Chem. Mater. (2021) (Li2CO3/LiNbO3-coated NCM622 with Li6PS5Cl).
doi: 10.1021/acs.chemmater.0c04660
checked 2026-11-03 F10.
korjus2025 Korjus et al., ACS Mater. Lett. 7 (2025) 2725 (a cell for operando neutron diffraction of solid-state batteries, NMC532 | Li6PS5Cl | Li0.5In).
doi: 10.1021/acsmaterialslett.5c00596
checked 2026-11-03 P5.
lu2024 X. Lu et al., Chem. Soc. Rev. 53 (2024) 4707 (microstructures and characterisation of Ni-rich cathodes, review).
doi: 10.1039/d3cs00741c
checked 2026-11-03 Background.