Octahedra volume ( \AA^{3}), main bond lengths ( \AA), selected angles ( { }^{\circ}) and bond-valence sum [86] for \mathrm{SrLa} \mathrm{MRuO}_{6}(\mathrm{M}=\mathrm{Zn}, \mathrm{Mg}) at room temperature.
| \mathrm{SrLaZnRuO}_{6} | \mathrm{SrLaMgRuO}_{6} | |
|---|---|---|
| \mathrm{MO}_{6} octahedra | ||
| \mathrm{V}\left(\mathrm{MO}_{6}\right) | 11.467(2) | 10.42(6) |
| M-O1( \times 2 ) | 2.048(6) | 1.99(4) |
| M-O2( \times 2 ) | 2.069(6) | 2.00(4) |
| M-O3( \times 2 ) | 2.034(9) | 1.97(6) |
| Average distance | 2.050(9) | 1.99(6) |
| Predicted distance | 2.1105 | 2.0995 |
| \mathrm{RuO}_{6} octahedra | ||
| \mathrm{V}\left(\mathrm{RuO}_{6}\right) | 10.195(3) | 10.51(5) |
| Ru-O1( \times 2 ) | 1.954(6) | 2.00(4) |
| Ru-O2( \times 2 ) | 1.972(6) | 1.95(4) |
| Ru-O3( \times 2 ) | 1.985(9) | 2.04(6) |
| Average distance | 1.971(9) | 2.00(6) |
| Predicted distance | 1.9675 | 1.9675 |
| <O1-M-O2 | 93.8(2) | 84.1(5) |
| LO1-M-O3 | 91.0(2) | 91.0(5) |
| LO2-M-O3 | 90.3(2) | 87.1(5) |
| CO1-Ru-O2 | 88.3(2) | 97.4(5) |
| CO1-Ru-O3 | 91.0(2) | 92.3(5) |
| CO2-Ru-O3 | 91.2(2) | 87.0(5) |
| \angle M-\mathrm{O} 1-\mathrm{Ru} | 162.8(2) | 160.1(6) |
| \angle M-\mathrm{O} 2-\mathrm{Ru} | 156.6(2) | 170.1(7) |
| \angle \mathrm{M}-\mathrm{O} 3-\mathrm{Ru} | 158.5(1) | 158.1(4) |
| Bond-Valence sum | ||
| M | 2.36(2) | 2.7(1) |
| Ru | 4.96(4) | 4.6(2) |