perovskite atlas Structures, modes and phase transitions · Josu M. Igartua · UPV/EHU

ALn2CuTi2O9 triple perovskites

status published · visibility public · id ser:a-ln2-cuti2o9

Template {A}{Ln}2CuTi2O9 · slots A ∈ {Ca, Ba}; Ln ∈ {La, Pr, Nd, Sm} · triple-perovskite · aristotype Pm3m

Members

material slots RT space group transitions primary irreps at RT (Å)
CaPr2CuTi2O9 A = Ca, Ln = Pr Pbnm R4+ 1.20(1), M3+ 1.03(1)
CaNd2CuTi2O9 A = Ca, Ln = Nd Pbnm R4+ 1.26(1), M3+ 0.96(1)
CaSm2CuTi2O9 A = Ca, Ln = Sm Pbnm R4+ 1.40(4), M3+ 1.09(4)
BaLa2CuTi2O9 A = Ba, Ln = La I4/mcm R4+ -0.27(6)
BaPr2CuTi2O9 A = Ba, Ln = Pr I4/mcm R4+ -0.37(8)
BaNd2CuTi2O9 A = Ba, Ln = Nd I4/mcm R4+ -0.35(9)

Evidence